Zinc was widely used in ancient times for both creating brass as well as healing wounds and sore eyes. In the later part of the 13th century Marco Polo witnessed the use of zinc by the Persians.
Romans were also to have been noted to have first created brass at the time of Augustus (20 BC to 14 AD). Brass that was created was seen as indistinguishable from gold.
Metallic zinc was first produced in India in about 1200 AD, seen only as a 'tin like' metal, but did differentiate it as a separate metal from the others... and thus the 8th metal was discovered. At this time there was only a limited amount of commercial zinc being produced. This metallic zinc that was produced was used for brass.
As demand for brass grew zinc production was moved to China [where else]. The Chinese were able commercially extract zinc which meant that it expanded and was imported to the world.
Zinc in Europe was quite accidental and linked to the manufacture of brass, again it was also used as an imitator of gold. By the 1600 European scientists were aware of the existence of zinc, tho it must be noted that this the zinc that they had was imported by either Dutch, Portuguese or Arab traders. From there European scientists learned from the Chinese and others how to mass produce zinc, from that zinc production began to grow.
Hot dip galvanising is the oldest anti corrosion process and was introduced in 1936 in France, but this only became effective on an industrial scale when there was a process to clean the surface of the steel. At first only small objects were coated in zinc... but later continuous hot dip galvanising of materials and products in manufacture came later.
I'm finding it extremely difficult to find early examples of zinc artifacts and that as it was used as an alloy to make brass. So while brass is easy to find... Zinc is not, perhaps it all disintegrated away.
anyone help?
Oh all the information that i used was from a paper by Fathi Habashi titled Zinc protects Discovering the 8th metal : A history of zinc.